Supported catalytic nanoparticles undergo rapid structural transformations faster than many transmission electron microscopes (TEMs) can track. This is the case with platinum nanoparticles supported on cerium oxide (Pt/CeO2) in a CO and O2 gaseous environment. By furthering our understanding of the structural dynamics of the Pt/CeO2 system, improved catalyst design principles may be derived to enhance the efficiency of this catalyst. Developing static models of a 2 nm Pt nanoparticle supported on CeO2 and simulating TEM images of the models was found to create similar images to those seen in experimental TEM time-resolved series of the system. Rotations of static models on a ceria support provides a way to understand the experimental samples in three dimensions, which is difficult in two dimensional TEM images. This project expands the possibilities of interpreting TEM images of catalytic systems.
Many nanotechnology-related principles can be demonstrated in a way that is understandable for elementary school-aged children through at-home activity videos. As a part of a National Science Foundation funded grant, Dr. Qing Hua Wang’s research group at Arizona State University developed a nanotechnology-related activity website, Nano@Home, for students. In conjunction with ASU’s virtual Open Door 2021, this creative project aimed to create activity videos based on the Nano@Home website to make the activities more interactive for students.
A novel concept for integration of flame-assisted fuel cells (FFC) with a gas turbine is analyzed in this paper. Six different fuels (CH4, C3H8, JP-4, JP-5, JP-10(L), and H2) are investigated for the analytical model of the FFC integrated gas turbine hybrid system. As equivalence ratio increases, the efficiency of the hybrid system increases initially then decreases because the decreasing flow rate of air begins to outweigh the increasing hydrogen concentration. This occurs at an equivalence ratio of 2 for CH4. The thermodynamic cycle is analyzed using a temperature entropy diagram and a pressure volume diagram. These thermodynamic diagrams show as equivalence ratio increases, the power generated by the turbine in the hybrid setup decreases. Thermodynamic analysis was performed to verify that energy is conserved and the total chemical energy going into the system was equal to the heat rejected by the system plus the power generated by the system. Of the six fuels, the hybrid system performs best with H2 as the fuel. The electrical efficiency with H2 is predicted to be 27%, CH4 is 24%, C3H8 is 22%, JP-4 is 21%, JP-5 is 20%, and JP-10(L) is 20%. When H2 fuel is used, the overall integrated system is predicted to be 24.5% more efficient than the standard gas turbine system. The integrated system is predicted to be 23.0% more efficient with CH4, 21.9% more efficient with C3H8, 22.7% more efficient with JP-4, 21.3% more efficient with JP-5, and 20.8% more efficient with JP-10(L). The sensitivity of the model is investigated using various fuel utilizations. When CH4 fuel is used, the integrated system is predicted to be 22.7% more efficient with a fuel utilization efficiency of 90% compared to that of 30%.
There is surprisingly little scientific literature describing whether a hockey slap shot positively or negatively transfers to a driving golf swing. Golf and hockey use a similar kinematic sequence to send the ball / puck towards a target, but does that directly translate to positive skill transfer between the two sports, or are there other important factors that could result in a negative skill transfer? The aim of this study is to look further into the two kinematic sequences and determine their intertask skill transfer type. A field experiment was conducted, following a specific research design, in order to compare performance between two groups, one being familiar with the skill that may transfer (hockey slapshot) and the other group being unfamiliar. Both groups had no experience in the skill being tested (driving golf swing) and various data was collected as all of the subjects performed 10 golf swings. The results of the data analysis showed that the group with experience in hockey had a higher variability of ball distance and ball speed. There are many factors of a hockey slapshot that are likely to develop a negative intertask skill transfer, resulting in this group's high inconsistency when performing a golf swing. On the other hand, the group with hockey experience also had higher mean club speed, showing that some aspects of the hockey slapshot resulted in a positive skill transfer, aiding their ability to perform a golf swing.
Soiled: An Environmental Podcast is a six episode series that addresses common environmental topics and debunks myths that surround those topics.
This is a study that demonstrates my growing understanding of the factors that influence Latinx engineering students’ sense of belonging in engineering. I conducted a literature review to help me gain perspectives from prior research on this topic. I wanted to investigate Latinx engineering students’ sense of belonging at Arizona State University. This interest was fueled by my own perspectives as an undergraduate first-generation Latina student. I was inspired by the Social Identity Development Theory described in “Becoming La Ingenieria” by Sarah L Rodriguez (2019). I found that science performance, science competence, and science identity recognition were important factors in engineering for Latinx students to thrive and succeed in their chosen major--engineering. Through the literature review, I found that Latinx engineering students need family support, faculty and staff to look up to, and ways to create authentic connections with near peers and professions. Student organization involvement such as in the Society of Hispanic Professional Engineers student chapter can help Latinx students grow their intersectional identities related to their identification as Latinx and as an engineer which then helped strengthen their sense of belonging in engineering. <br/><br/>I conducted a survey of Latinx engineering students at Arizona State University to better understand their perceptions on issues related to their sense of belonging and underlying factors of competence, recognition, and performance in engineering. However, due to the low participation, possibly due to the ongoing COVID-19 pandemic, I could not conduct statistical analyses that could lead inferences to the broad population of Latinx engineering students at ASU. <br/><br/>It is important to continue to create structures within university engineering programs and professional engineering societies to offer formal near-peer and professional mentorship of Latinx students. The integration of families from recruitment to graduation of Latinx engineering students may help build a more supportive structure for students to succeed. Research on the ways in which university faculty, staff, and near-peers can better support Latinx students will be essential to build classroom environments that help all students build a sense of belonging in engineering.