Matching Items (108)
Description

The recent discoveries of 2D van der Waals (vdW) materials have led to the realization of 2D magnetic crystals. Previously debated and thought impossible, transition metal halides (TMH) have given rise to layer dependent magnetism. Using these TMH as a basis, an alloy composing of Fe1-xNixCl2 (where 0 ≤ x

The recent discoveries of 2D van der Waals (vdW) materials have led to the realization of 2D magnetic crystals. Previously debated and thought impossible, transition metal halides (TMH) have given rise to layer dependent magnetism. Using these TMH as a basis, an alloy composing of Fe1-xNixCl2 (where 0 ≤ x ≤ 1) was grown using chemical vapor transport. The intrigue for this alloy composition stems from the interest in spin canting and magnet moment behavior since NiCl2 has in-plane ferromagnetism whereas FeCl2 has out-of-plane ferromagnetism. While in its infancy, this project lays out a foundation to fully develop and characterize this TMH via cationic alloying. To study the magnetic properties of this alloy system, Vibrating Sample Magnetometry was employed extensively to measure the magnetism as a function of temperature as well as applied magnetic field. Future work with use a combination of X-Ray Diffraction, Raman, Scanning Electron Microscopy, and Energy-Dispersive X-Ray Spectroscopy Mapping to verify homogeneous alloying rather than phase separation. Additionally, ellipsometry will be used with Kramer-Kronig relations to extract the dielectric constant from Fe1-xNixCl2. This work lays the foundation for future, fruitful work to prepare this vdW cationic alloy for eventual device applications.

ContributorsPovilus, Blake (Author) / Tongay, Sefaattin (Thesis director) / Yang, Sui (Committee member) / Barrett, The Honors College (Contributor) / Materials Science and Engineering Program (Contributor)
Created2022-05
Description
With the growth of the additive manufacturing (AM) industry for metal components, there is an economic pressure for improved AM processes to overcome the shortcomings of current AM technologies (i.e., limited deposition rates, surface roughness, etc.). Unfortunately, the development of these processes can be time and capital-intensive due to the large

With the growth of the additive manufacturing (AM) industry for metal components, there is an economic pressure for improved AM processes to overcome the shortcomings of current AM technologies (i.e., limited deposition rates, surface roughness, etc.). Unfortunately, the development of these processes can be time and capital-intensive due to the large number of input parameters and the sensitivity of the process’s outputs to said inputs. There consequently has been a strong push to develop computational design tools (such as CFD models) which can decrease the time and cost of AM technology developments. However, many of the developments that have been made to simulate AM through CFD have done so on custom CFD packages (as opposed to commercially available packages), which increases the barrier to entry of employing computational design tools. For that reason, this paper has demonstrated a method for simulating fused deposition modeling using a commercially available CFD package (Fluent). The results from this implementation are qualitatively promising when compared to samples produced by existing metal AM processes, however additional work is needed to validate the model more rigorously and to reduce the computational cost. Finally, the developed model was used to perform a parameter sweep, thereby demonstrating a use case of the tool to help in parameter optimization.
Created2024-05
Description

Startups in the paper manufacturing industry are few and far between. Agrix paper takes a step towards innovating the traditional mass-scale paper making process and introduces non-wood fiber sourcing into the papermaking space. Using a hemp fiber base, Agrix Paper hopes to develop a new paper manufacturing process that derives

Startups in the paper manufacturing industry are few and far between. Agrix paper takes a step towards innovating the traditional mass-scale paper making process and introduces non-wood fiber sourcing into the papermaking space. Using a hemp fiber base, Agrix Paper hopes to develop a new paper manufacturing process that derives high-quality paper sourced from hemp and agriculture waste. Agrix Paper will reinvent the papermaking process for a more green and sustainable future.

ContributorsByrum, Emily (Author) / DiFernando, Anthony (Co-author) / Barraza-Córdova, Erik (Co-author) / Bryne, Jared (Thesis director) / Lee, Christopher (Committee member) / Barrett, The Honors College (Contributor) / Department of Physics (Contributor) / School for Engineering of Matter,Transport & Enrgy (Contributor)
Created2023-05
Description

To mitigate climate change, carbon needs to be removed from the atmosphere and stored for thousands of years. Currently, carbon removal and storage are voluntarily procured, and longevity of storage is inconsistently defined and regulated. Clauses can be added to procurement contracts to require long-term management and increase the durability

To mitigate climate change, carbon needs to be removed from the atmosphere and stored for thousands of years. Currently, carbon removal and storage are voluntarily procured, and longevity of storage is inconsistently defined and regulated. Clauses can be added to procurement contracts to require long-term management and increase the durability of storage. Well-designed and properly enforced contracts can pave the way to future regulation for long-term carbon management.

ContributorsHagood, Emily (Author) / Lackner, Klaus (Thesis director) / Marchant, Gary (Committee member) / Barrett, The Honors College (Contributor) / Materials Science and Engineering Program (Contributor) / School of Mathematical and Statistical Sciences (Contributor) / School of Sustainability (Contributor)
Created2023-05
Description

The environment today is facing concerns over accumulation of plastics in landfills as well as excessive CO2 emissions. Containers and packaging take up approximately 15 million tons each year, and accumulations such as the Great Pacific Garbage Patch are entering the oceans. Work has been done to alter and treat

The environment today is facing concerns over accumulation of plastics in landfills as well as excessive CO2 emissions. Containers and packaging take up approximately 15 million tons each year, and accumulations such as the Great Pacific Garbage Patch are entering the oceans. Work has been done to alter and treat polyethylene plastic to be added to cement mixtures. This is done to increase bearing capacity and ductility of concrete in addition to decreasing carbon emissions and plastic waste.

ContributorsWestersund, Susanna (Author) / Hoover, Christian (Thesis director) / Soman, Silpa (Committee member) / Barrett, The Honors College (Contributor) / Materials Science and Engineering Program (Contributor) / Civil, Environmental and Sustainable Eng Program (Contributor)
Created2023-05
Description

Protein and gene circuit level synthetic bioengineering can require years to develop a single target. Phage assisted continuous evolution (PACE) is a powerful new tool for rapidly engineering new genes and proteins, but the method requires an automated cell culture system, making it inaccessible to non industrial research programs. Complex

Protein and gene circuit level synthetic bioengineering can require years to develop a single target. Phage assisted continuous evolution (PACE) is a powerful new tool for rapidly engineering new genes and proteins, but the method requires an automated cell culture system, making it inaccessible to non industrial research programs. Complex protein functions, like specific binding, require similarly dynamic PACE selection that can be alternatively induced or suppressed, with heat labile chemicals like tetracycline. Selection conditions must be controlled continuously over days, with adjustments made every few minutes. To make PACE experiments accessible to the broader community, we designed dedicated cell culture hardware and integrated optogenetically controlled plasmids. The low cost and open source platform allows a user to conduct PACE with continuous monitoring and precise control of evolution using light.

ContributorsTse, Ashley (Author) / Bartelle, Benjamin (Thesis director) / Tian, Xiaojun (Committee member) / Barrett, The Honors College (Contributor) / Materials Science and Engineering Program (Contributor) / School of International Letters and Cultures (Contributor) / Harrington Bioengineering Program (Contributor)
Created2023-05
Description

DNA is useful for electronic applications due to its self-assembly and electronic properties. It can be improved for this purpose through the addition of metal ions. In this experiment, DNA was modified with silver ions and carbon nanotubes were attached to both ends. The DNA-CNTs were connected over a 300

DNA is useful for electronic applications due to its self-assembly and electronic properties. It can be improved for this purpose through the addition of metal ions. In this experiment, DNA was modified with silver ions and carbon nanotubes were attached to both ends. The DNA-CNTs were connected over a 300 nm gap between gold electrodes using cysteamine. The conductance was found to be 1.28*10-4 G0, which is similar to literature values for unmodified DNA. Therefore, modifying DNA with silver ions was not found to significantly improve the conductance. It was also found that smaller applied voltages need to be used because of electrochemistry happening above 1 V.

ContributorsAbbas, Isabelle (Author) / Forzani, Erica (Thesis director) / Hihath, Joshua (Committee member) / Barrett, The Honors College (Contributor) / Chemical Engineering Program (Contributor) / Materials Science and Engineering Program (Contributor)
Created2023-05
Description
Transition metal dichalcogenides (TMDs) are a family of layered crystals with the chemical formula MX2 (M = W, Nb, Mo, Ta and X = S, Se, Te). These TMDs exhibit many fascinating optical and electronic properties making them strong candidates for high-end electronics, optoelectronic application, and spintronics. The layered structure

Transition metal dichalcogenides (TMDs) are a family of layered crystals with the chemical formula MX2 (M = W, Nb, Mo, Ta and X = S, Se, Te). These TMDs exhibit many fascinating optical and electronic properties making them strong candidates for high-end electronics, optoelectronic application, and spintronics. The layered structure of TMDs allows the crystal to be mechanically exfoliated to a monolayer limit, where bulk-scale properties no longer apply and quantum effects arise, including an indirect-to-direct bandgap transition. Controllably tuning the electronic properties of TMDs like WSe2 is therefore a highly attractive prospect achieved by substitutionally doping the metal atoms to enable n- and p-type doping at various concentrations, which can ultimately lead to more effective electronic devices due to increased charge carriers, faster transmission times and possibly new electronic and optical properties to be probed. WSe2 is expected to exhibit the largest spin splitting size and spin-orbit coupling, which leads to exciting potential applications in spintronics over its similar TMD counterparts, which can be controlled through electrical doping. Unfortunately, the well-established doping technique of ion implantation is unable to preserve the crystal quality leading to a major roadblock for the electronics applications of tungsten diselenide. Synthesizing WSe2 via chemical vapor transport (CVT) and flux method have been previously established, but controllable p-type (niobium) doping WSe2 in low concentrations ranges (<1 at %) by CVT methods requires further experimentation and study. This work studies the chemical vapor transport synthesis of doped-TMD W1-xNbxSe2 through characterization techniques of X-ray Diffraction, Scanning Electron Microscopy, Energy Dispersive X-ray Spectroscopy, and X-ray Photoelectron Spectroscopy techniques. In this work, it is observed that excess selenium transport does not enhance the controllability of niobium doping in WSe2, and that tellurium tetrachloride (TeCl4) transport has several barriers in successfully incorporating niobium into WSe2.
ContributorsRuddick, Hayley (Author) / Tongay, Sefaattin (Thesis director) / Jiao, Yang (Committee member) / Barrett, The Honors College (Contributor) / Materials Science and Engineering Program (Contributor)
Created2024-05
Description

Most asteroids originated in larger parent bodies that underwent accretion and heating during the first few million years of the solar system. We investigated the parent body of S-type asteroid 25143 Itokawa by developing a computational model which can approximate the thermal evolution of an early solar system body. We

Most asteroids originated in larger parent bodies that underwent accretion and heating during the first few million years of the solar system. We investigated the parent body of S-type asteroid 25143 Itokawa by developing a computational model which can approximate the thermal evolution of an early solar system body. We compared known constraints on Itokawa’s thermal history to simulations of its parent body and constrained its time of formation to between 1.6 and 2.5 million years after the beginning of the solar system, though certain details could allow for even earlier or later formation. These results stress the importance of precise data required of the material properties of asteroids and meteorites to place better constraints on the histories of their parent bodies. Additional mathematical and computational details are discussed, and the full code and data is made available online.

ContributorsHallstrom, Jonas (Author) / Bose, Maitrayee (Thesis director) / Beckstein, Oliver (Committee member) / Barrett, The Honors College (Contributor) / Department of Physics (Contributor) / Materials Science and Engineering Program (Contributor)
Created2023-05
Description

Sun Stop Solar, is a solar module development and manufacturing company that utilizes a unique class of materials, perovskites, as the solar cells’ absorption layer. Perovskites are a unique class of compounds with some perovskites being able to absorb photons and excite electrons to create current. Sun Stop Solar plans

Sun Stop Solar, is a solar module development and manufacturing company that utilizes a unique class of materials, perovskites, as the solar cells’ absorption layer. Perovskites are a unique class of compounds with some perovskites being able to absorb photons and excite electrons to create current. Sun Stop Solar plans to initially begin by developing the foundational technological patent for our perovskite-based single-junction solar cells. Sun Stop Solar plans to initially begin by first having a patent set up, then licensing our patent to a manufacturer, and slowly building towards manufacturing our own solar modules.

ContributorsMatyushov, Ivan (Author) / Aboudi, Joseph (Co-author) / Hofer, David (Co-author) / Byrne, Jared (Thesis director) / Lawson, Brennan (Committee member) / Cartwright, Bryce (Committee member) / Adarsh, Siddharth (Committee member) / Higashino, Katsuko (Committee member) / Barrett, The Honors College (Contributor) / Materials Science and Engineering Program (Contributor)
Created2023-05