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To mitigate climate change, carbon needs to be removed from the atmosphere and stored for thousands of years. Currently, carbon removal and storage are voluntarily procured, and longevity of storage is inconsistently defined and regulated. Clauses can be added to procurement contracts to require long-term management and increase the durability

To mitigate climate change, carbon needs to be removed from the atmosphere and stored for thousands of years. Currently, carbon removal and storage are voluntarily procured, and longevity of storage is inconsistently defined and regulated. Clauses can be added to procurement contracts to require long-term management and increase the durability of storage. Well-designed and properly enforced contracts can pave the way to future regulation for long-term carbon management.

ContributorsHagood, Emily (Author) / Lackner, Klaus (Thesis director) / Marchant, Gary (Committee member) / Barrett, The Honors College (Contributor) / Materials Science and Engineering Program (Contributor) / School of Mathematical and Statistical Sciences (Contributor) / School of Sustainability (Contributor)
Created2023-05
Description

The environment today is facing concerns over accumulation of plastics in landfills as well as excessive CO2 emissions. Containers and packaging take up approximately 15 million tons each year, and accumulations such as the Great Pacific Garbage Patch are entering the oceans. Work has been done to alter and treat

The environment today is facing concerns over accumulation of plastics in landfills as well as excessive CO2 emissions. Containers and packaging take up approximately 15 million tons each year, and accumulations such as the Great Pacific Garbage Patch are entering the oceans. Work has been done to alter and treat polyethylene plastic to be added to cement mixtures. This is done to increase bearing capacity and ductility of concrete in addition to decreasing carbon emissions and plastic waste.

ContributorsWestersund, Susanna (Author) / Hoover, Christian (Thesis director) / Soman, Silpa (Committee member) / Barrett, The Honors College (Contributor) / Materials Science and Engineering Program (Contributor) / Civil, Environmental and Sustainable Eng Program (Contributor)
Created2023-05
Description

Protein and gene circuit level synthetic bioengineering can require years to develop a single target. Phage assisted continuous evolution (PACE) is a powerful new tool for rapidly engineering new genes and proteins, but the method requires an automated cell culture system, making it inaccessible to non industrial research programs. Complex

Protein and gene circuit level synthetic bioengineering can require years to develop a single target. Phage assisted continuous evolution (PACE) is a powerful new tool for rapidly engineering new genes and proteins, but the method requires an automated cell culture system, making it inaccessible to non industrial research programs. Complex protein functions, like specific binding, require similarly dynamic PACE selection that can be alternatively induced or suppressed, with heat labile chemicals like tetracycline. Selection conditions must be controlled continuously over days, with adjustments made every few minutes. To make PACE experiments accessible to the broader community, we designed dedicated cell culture hardware and integrated optogenetically controlled plasmids. The low cost and open source platform allows a user to conduct PACE with continuous monitoring and precise control of evolution using light.

ContributorsTse, Ashley (Author) / Bartelle, Benjamin (Thesis director) / Tian, Xiaojun (Committee member) / Barrett, The Honors College (Contributor) / Materials Science and Engineering Program (Contributor) / School of International Letters and Cultures (Contributor) / Harrington Bioengineering Program (Contributor)
Created2023-05
Description

DNA is useful for electronic applications due to its self-assembly and electronic properties. It can be improved for this purpose through the addition of metal ions. In this experiment, DNA was modified with silver ions and carbon nanotubes were attached to both ends. The DNA-CNTs were connected over a 300

DNA is useful for electronic applications due to its self-assembly and electronic properties. It can be improved for this purpose through the addition of metal ions. In this experiment, DNA was modified with silver ions and carbon nanotubes were attached to both ends. The DNA-CNTs were connected over a 300 nm gap between gold electrodes using cysteamine. The conductance was found to be 1.28*10-4 G0, which is similar to literature values for unmodified DNA. Therefore, modifying DNA with silver ions was not found to significantly improve the conductance. It was also found that smaller applied voltages need to be used because of electrochemistry happening above 1 V.

ContributorsAbbas, Isabelle (Author) / Forzani, Erica (Thesis director) / Hihath, Joshua (Committee member) / Barrett, The Honors College (Contributor) / Chemical Engineering Program (Contributor) / Materials Science and Engineering Program (Contributor)
Created2023-05
Description
Transition metal dichalcogenides (TMDs) are a family of layered crystals with the chemical formula MX2 (M = W, Nb, Mo, Ta and X = S, Se, Te). These TMDs exhibit many fascinating optical and electronic properties making them strong candidates for high-end electronics, optoelectronic application, and spintronics. The layered structure

Transition metal dichalcogenides (TMDs) are a family of layered crystals with the chemical formula MX2 (M = W, Nb, Mo, Ta and X = S, Se, Te). These TMDs exhibit many fascinating optical and electronic properties making them strong candidates for high-end electronics, optoelectronic application, and spintronics. The layered structure of TMDs allows the crystal to be mechanically exfoliated to a monolayer limit, where bulk-scale properties no longer apply and quantum effects arise, including an indirect-to-direct bandgap transition. Controllably tuning the electronic properties of TMDs like WSe2 is therefore a highly attractive prospect achieved by substitutionally doping the metal atoms to enable n- and p-type doping at various concentrations, which can ultimately lead to more effective electronic devices due to increased charge carriers, faster transmission times and possibly new electronic and optical properties to be probed. WSe2 is expected to exhibit the largest spin splitting size and spin-orbit coupling, which leads to exciting potential applications in spintronics over its similar TMD counterparts, which can be controlled through electrical doping. Unfortunately, the well-established doping technique of ion implantation is unable to preserve the crystal quality leading to a major roadblock for the electronics applications of tungsten diselenide. Synthesizing WSe2 via chemical vapor transport (CVT) and flux method have been previously established, but controllable p-type (niobium) doping WSe2 in low concentrations ranges (<1 at %) by CVT methods requires further experimentation and study. This work studies the chemical vapor transport synthesis of doped-TMD W1-xNbxSe2 through characterization techniques of X-ray Diffraction, Scanning Electron Microscopy, Energy Dispersive X-ray Spectroscopy, and X-ray Photoelectron Spectroscopy techniques. In this work, it is observed that excess selenium transport does not enhance the controllability of niobium doping in WSe2, and that tellurium tetrachloride (TeCl4) transport has several barriers in successfully incorporating niobium into WSe2.
ContributorsRuddick, Hayley (Author) / Tongay, Sefaattin (Thesis director) / Jiao, Yang (Committee member) / Barrett, The Honors College (Contributor) / Materials Science and Engineering Program (Contributor)
Created2024-05
Description

Most asteroids originated in larger parent bodies that underwent accretion and heating during the first few million years of the solar system. We investigated the parent body of S-type asteroid 25143 Itokawa by developing a computational model which can approximate the thermal evolution of an early solar system body. We

Most asteroids originated in larger parent bodies that underwent accretion and heating during the first few million years of the solar system. We investigated the parent body of S-type asteroid 25143 Itokawa by developing a computational model which can approximate the thermal evolution of an early solar system body. We compared known constraints on Itokawa’s thermal history to simulations of its parent body and constrained its time of formation to between 1.6 and 2.5 million years after the beginning of the solar system, though certain details could allow for even earlier or later formation. These results stress the importance of precise data required of the material properties of asteroids and meteorites to place better constraints on the histories of their parent bodies. Additional mathematical and computational details are discussed, and the full code and data is made available online.

ContributorsHallstrom, Jonas (Author) / Bose, Maitrayee (Thesis director) / Beckstein, Oliver (Committee member) / Barrett, The Honors College (Contributor) / Department of Physics (Contributor) / Materials Science and Engineering Program (Contributor)
Created2023-05
Description

Sun Stop Solar, is a solar module development and manufacturing company that utilizes a unique class of materials, perovskites, as the solar cells’ absorption layer. Perovskites are a unique class of compounds with some perovskites being able to absorb photons and excite electrons to create current. Sun Stop Solar plans

Sun Stop Solar, is a solar module development and manufacturing company that utilizes a unique class of materials, perovskites, as the solar cells’ absorption layer. Perovskites are a unique class of compounds with some perovskites being able to absorb photons and excite electrons to create current. Sun Stop Solar plans to initially begin by developing the foundational technological patent for our perovskite-based single-junction solar cells. Sun Stop Solar plans to initially begin by first having a patent set up, then licensing our patent to a manufacturer, and slowly building towards manufacturing our own solar modules.

ContributorsMatyushov, Ivan (Author) / Aboudi, Joseph (Co-author) / Hofer, David (Co-author) / Byrne, Jared (Thesis director) / Lawson, Brennan (Committee member) / Cartwright, Bryce (Committee member) / Adarsh, Siddharth (Committee member) / Higashino, Katsuko (Committee member) / Barrett, The Honors College (Contributor) / Materials Science and Engineering Program (Contributor)
Created2023-05
Description

The 1970’s was an exciting time for those interested in avian navigation and magnetoreception. In the mid 1970’s, it had been scientifically proven that birds utilized the Earth’s magnetic fields as a means for orientation. However, while scientists now knew that birds could detect geomagnetic fields, a major question still

The 1970’s was an exciting time for those interested in avian navigation and magnetoreception. In the mid 1970’s, it had been scientifically proven that birds utilized the Earth’s magnetic fields as a means for orientation. However, while scientists now knew that birds could detect geomagnetic fields, a major question still remained: how? Several years later, physicist Klaus Schulten would bring the world much closer to an answer with the introduction of the radical pair model. With an extremely firm grasp of quantum mechanics, Schulten was able to make an amazing connection between the magnetically sensitive “radical pairs” and magnetic sensing in organisms (such as birds). The goal of this thesis is to explore this intersection of quantum mechanics and biology first illuminated by Schulten, through providing an in-depth explanation of the radical pair model itself, the quantum mechanical concepts that allow it to exist, the possible biological structures involved, and a small exploration of where the theory stands today, all to better understand the fascinating phenomenon of avian magnetoreception.

ContributorsFelix, Lia (Author) / Foy, Joseph (Thesis director) / Martin, Thomas (Committee member) / Barrett, The Honors College (Contributor) / Materials Science and Engineering Program (Contributor)
Created2022-05
Description

Computational materials is a field that utilizes modeling, simulations, and technology to study how materials behave. This honors thesis is a presentation discussing computational materials, our study of packing theory using the Monte Carlo (MC), and how our research can be related to real materials we use.

ContributorsVidallon, Justine Ilyssa (Author) / Jiao, Yang (Thesis director) / Zhuang, Houlong (Committee member) / Barrett, The Honors College (Contributor) / Materials Science and Engineering Program (Contributor)
Created2023-05
Description

Stress for college students is nothing new and as more kids go to college the number of cases are on the rise. This issue is apparent at colleges across the nation including Arizona State University. StreetWise aims to help students prevent or appropriately deal with stress through interactive lessons teaching

Stress for college students is nothing new and as more kids go to college the number of cases are on the rise. This issue is apparent at colleges across the nation including Arizona State University. StreetWise aims to help students prevent or appropriately deal with stress through interactive lessons teaching students life skills, social skills, and emotional intelligence.<br/>In order to prove the value of our service, StreetWise conducted a survey that asked students about their habits, thoughts on stress, and their future. Students from Arizona State University were surveyed with questions on respondent background, employment, number one stressor, preferred learning method, and topics that students were interested in learning. We found that students’ number one stressor was school but was interested in learning skills that would prepare them for their future after graduation. We used the results to make final decisions so that StreetWise could offer lessons that students would get the most value out of. This led to us conducting a second survey which included mock ups of the website, examples of interactive lesson plans, and an overview of the app. Students from the first survey were surveyed in addition to new respondents. This survey was intended for us to ensure that our service would maintain its value to students with the aesthetic and interface that we envisioned.

ContributorsWard, William Henry (Co-author) / Ahir, Hiral (Co-author) / Compton, Katherine (Co-author) / Byrne, Jared (Thesis director) / Hall, Rick (Committee member) / Materials Science and Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2021-05